Adam,
I do appreciate the thought of placing this information in the Email Alert Settings of the gui, but understand, I HAVE done this, and this is NOT the problem.
Also, to follow along with your first suggestion seems more probable to my problem, and has been attempted. The one thing I am concerned with is the comment contained within the code,
[email]
"from email address (name only, host will be appended automatically from mailserver)"
It specifically states to use the NAME to auth ONLY. Even still I have tried both, but still same problem with how Splunk tries to auth with the server.
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